There are 4 Villains in this collection. Unfortunately, I could only get a couple of items from this collection, because everything sold out. So, these are the items I could get my hands on.
Cruella De Vil, from Disney's 1961 101 Dalmatians. The only thing I got from this Villain is Mac's eye shadow in Carbon, which is in there permanent line. It is a intense black.
Evil Queen, from Disney's 1937 Snow White. I got the vain queen's eyeshadow in Her Alter Image, which is a light violet. This color is Limited Edition.
Maleificent, from 1959's Sleeping Beauty. From the "Mistress Of All Evil" I got Briar Rose Beauty Powder. Which is a soft violet pink with pearl. And if a special limited edition.
Dr. Facilier, the voodoo witch doctor from the 2009 The Princess And The Frog. I got Mac's Melon Pigment, which is a soft bright golden peach. And is in there permanent collection. I also purchased I'm So Vain Mirror. A black round compact featuring 2 mirrors:regular/magnify. With Dr. Facilier decorating the limited edition mirror.